Title |
Temperature Dependence of Energy Gap and Thermodynamic Function Properties of Undoped and Co-doped Cd_{4}GeSe_{6} Sing1e Crystals by Chemical Transport Reaction Method |
Authors |
김남오(Kim, Nam-Oh) ; 김형곤(Kim, Hyung-Gon) ; 김덕태(Kim, Duck-Tae) ; 현승철(Hyun, Seung-Cheol) ; 오금곤(Oh, Gum-Kon) |
Keywords |
entropy ; enthalpy ; heat capacity ; optical energy gap ; Varshni equation |
Abstract |
In this work Cd_{4}GeSe_{6} and Cd_{4}GeSe_{6} : Co^{2+} single crystals were grown by the chemical transport reaction method and the structure of Cd_{4}GeSe_{6} and Cd_{4}GeSe_{6} : Co^{2+} single crystals were monoclinic structure. The temperature dependence of optical energy 9ap was fitted well to Varshni equation. Also, the entropy, enthalpy and heat capacity were deduced from the temperature dependence of optical energy gap. |